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N i t r o g e n m a k e s u p t h e m a j o r p o r t i o n o f t h e a t m o s p h e r e ( 7 8 . 0 3 % b y v o l u m e , 7 5 . 5 % b y w e i g h t ) . G a s e o u s n i t r o g e n i s i n e r t , c o l o r l e s s , o d o r l e s s , t a s t e l e s s , n o n t o x i c , n o n c o r r o s i v e , a n d n o n f l a m m a b l e . N i t r o g e n i s i n e r t a n d w i l l n o t s u p p o r t c o m b u s t i o n ; h o w e v e r , i t i s n o t l i f e s u p p o r t i n g .
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N i t r o g e n i s t h e l a r g e s t v o l u m e i n o r g a n i c c h e m i c a l s o l d i n t h e w o r l d a n d h a s a m u l t i t u d e o f c o m m e r c i a l a n d t e c h n i c a l a p p l i c a t i o n s . N i t r o g e n s p r o p e r t i e s b e n e f i t a p p l i c a t i o n s s u c h a s h e a t t r e a t i n g a t m o s p h e r e s , b l a n k e t i n g a t m o s p h e r e s , p r o p e l l a n t s , p n e u m a t i c s , p u r g i n g a n d p r e s s u r i z i n g , a n d a n a l y t i c a l c a r r i e r g a s e s .
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B e i n g o d o r l e s s , c o l o r l e s s , t a s t e l e s s , a n d n o n - i rritating, nitrogen has no warning properties. Humans possess no senses that can detect the presence of nitrogen. Although nitrogen is nontoxic and largely inert, it can act as a simple asphyxiant by displacing the oxygen in air to levels below that required to support life. Inhalation of nitrogen in excessive amounts can cause dizziness, nausea, vomiting, loss of consciousness, and death. Death may result from errors in judgment, confusion, or loss of consciousness, which prevents self-rescue. At low oxygen concentrations, unconsciousness and death may occur in seconds and without
warning. Personnel, including rescue workers, should not enter areas where the oxygen concentration is below 19.5%, unless provided with a self-contained breathing apparatus or air-line respirator.
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G a s e o u s n i t r o g e n i s s h i p p e d a n d s t o r e d i n h i g h - p r e s s u r e c y l i n d e r s , t u b e s , o r t ube trailers depending upon the quantity required by the user. Containers are designed and manufactured according to applicable codes and specifications for the pressures and temperatures involved. The quantity of product a container can hold is determined by its water capacity and pressure rating.
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A c y l i n d e r ( F i g . 1 ) i s a h o l l o w t u b e w i t h a c l o s e d c o n c a v e b a s e t h a t p e r m i t s t h e c y l i n d e r t o s t a n d u p r i g h t . T h e o p p o s i t e e n d i s t a p e r e d t o a s m a l l o p e n i n g , w h i c h i s t h r e a d e d t o a c c o m m o d a t e t h e i n s t a l l a t i o n o f a v a l v e . A t h r e a d e d n e c k r i n g i s a t t a c h e d t o t h e t a p e r e d e n d t o a l l o w a p r o t e c t i v e c y l i n d e r c a p t o b e i n s t a l l e d .
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C y l i n d e r s a r e m a n u f a c t u r e d a c c o r d i n g t o D O T r e g u l a t i o n s . T h e s e r e g u l a t i o n s s p e c i f y t h e m a t e r i a l o f c o n s t r u c t i o n , m e t h o d o f m a n u f a c t u r e , m e t h o d o f t e s t i n g , w h a t p r o d u c t s t h e y a r e p e r m i t t e d t o b e f i l l e d w i t h , a s w e l l a s o t h e r d e t a i l s .
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C y l i n d e r s m a y b e u s e d i n d i v i d u a l l y o r i n g r o u p s . W h e n i n g r o u p s , t h e c y l i n d e r s s h o u l d b e p i p e d t o g e t h e r , f o r s t a t i o n a r y s t o r a g e o r t o f o r m p o r t a b l e b a n k s .
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A t u b e ( F i g . 2 ) i s a p i p e t h a t i s t a p e r e d o n b o t h e n d s . E a c h e n d i s t h e n t h r e a d e d t o a l l o w t h e i n s t a l l a t i o n o f v a l v e s , c o n n e c t i o n s , o r r e l i e f d e v i c e s .
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T u b e s a r e m a n u f a c t u r e d a c c o r d i n g t o D O T r e g u l a t i o n s o r t h e y m a y b e m a d e t o A S M E c o d e s , d e p e n d i n g o n w h e t h e r t h e y a r e u s e d f o r t r a n s p o r t a t i o n o r m o u n t e d p e r m a n e n t l y a t a s i t e . T u b e s a r e g e n e r a l l y m o u n t e d o n t r u c k - t r a i l e r c h a s s i s o r r a i l r o a d c a r b e d s , o r p l a c e d a t s t a t i o n a r y l o c a t i o n s w h e n l a r g e a m o u n t s o f n i t r o g e n a r e n e e d e d .
9hncS/f(u嶯袕搹b8lEN塠艌(W術Y cgqD O T 剉膲歔bA S M E 剉膲歔6R 悺{S0S N,/f塠艌(W謆f彆^豽b gh廸彆^
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T h e C o m p r e s s e d G a s A s s o c i a t i o n ( C G A ) r e c o m m e n d s t h r e e d i f f e r e n t c o n n e c t i o n s f o r n i t r o g e n d e p e n d i n g o n t h e p r e s s u r e o f t h e c o n t a i n e r . I n a d d i t i o n , a h i g h - i n t e g r i t y c o n n e c t i o n k n o w n a l s o a s a Diameter Index Safety System (DISS) connection has also been assigned to nitrogen. Cylinders containing nitrogen at pressures up to 3000 psig use a CGA 580 connection; cylinders containing pressures between 3001 and5500 psig use a CGA 680 connection; and cylinders containing pressures between 5501and 7500 psig use a CGA 677 connection. The DISS connection assigned to nitrogen is DISS718. For detailed drawings of these connections, consult CGA Pamphlet V-1. For general drawings consult the Air Products Spe c i a l t y G a s e s a n d E q u i p m e n t C a t a l o g .
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N i t r o g e n c o n t a i n e r s a r e e q u i p p e d w i t h p r e s s u r e r e l i e f d e v i c e s t o p r o t e c t f r o m o v e r p r e s s u r i z a t i o n . N i t r o g e n c y l i n d e r s l e s s t h a n 6 5 i n c h e s l o n g u s e a f r a n g i b l e d i s c d e v i c e . C y l i n d e r s o v e r 6 5 i n c h e s u se a combination device consisting of a frangible disc backed by a fusible alloy. Combination devices require that both the temperature and pressure requirements be reached before the device will relieve. For more information on pressure relief devices, consult Air Products Safetygram-15, 揅ylinder Pressure Relief Devices.
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A l l s h i p m e n t s o f c o m p r e s s e d n i t r o g e n m u s t c o m p l y w i t h D O T r e g u l a t i o n s . T h i s i s t r u e f o r m o t o r f r e i g h t , r a i l , w a ter, and air shipments. The Department of Transportation Regulations, Title49, also describes the labeling and identification required. All packaging used to transport nitrogen must be either 揢N/DOT Specification or 揢N/DOT Authorized and in proper condition for transport.
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